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闫晓宇 副教授




专业:有机化学


电子邮件:yanxy(at)chem.ruc.edu.cn

网站:Group主页


教育和工作背景:

2004.9-2008.7 清华大学化学系 本科

2008.9-2013.7 清华大学化学系 博士

2008.1-2008.3 日本北海道大学 访问学生

2010.9-2011.9 美国加州大学河滨分校 访问学生

2013.8-2014.1 清华大学化学系 研究助理

2014.2-2016.1 德国维尔茨堡大学 洪堡学者,博士后

2016.2至今 中国人民大学化学系 副教授


研究兴趣:

金属导向的有机合成方法学

主族元素有机化学及其配合物的合成

代表性论文:

1. Yan, X.; Xi, C.* Multifaceted Zirconate Complexes in Organic Synthesis, Coord. Chem. Rev. 2016, 308, 22.

2. Yan, X.; Xi, C.*Conversion of Zirconacyclopentadienes into Metalloles: Fagan-Nugent Reaction and Beyond, Acc. Chem. Res., 2015, 48, 935.

3. Yan, X.; Yang, X.; Xi, C.* Recent progress in copper-catalyzed electrophilic amination. Catal. Sci. Technol. 2014, 4, 4169.

4. Yan, X.; Yi, X.; Xi, C.* Direct cleavage of the N=N bond of azobenzenes by MeOTf leading to N-arylbenzimidazoles. Org. Chem. Front. 2014, 1, 657.

5. Yan, X.; Chen, C.; Xi, C.* Zirconoarylation of alkynes through p-chloranil-promoted reductive elimination of arylzirconates. Beilstein J. Org. Chem. 2014, 10, 528.

6. Yan, X.; Zou, S.; Zhao, P.; Xi, C.* MeOTf-induced carboannulation of arylnitriles and aromatic alkynes: a new metal-free strategy to construct indenones. Chem. Commun. 2014, 50, 2775.

7. Yan, X.; Fang, K.; Liu, H.; Xi, C.* Copper-catalyzed oxidation of arene-fused cyclic amines to cyclic imides. Chem. Commun. 2013, 49, 10650.

8. Yan, X.; Zhou, Y.; Xi, C.* Reactivity of Alkynylzirconate toward α,β-Unsaturated Carbonyl Compounds. Organometallics 2013, 32, 869.

9. Yan, X.; Chen, C.;* Zhou, Y.; Xi, C.* Copper-Catalyzed Electrophilic Amination of Alkenylzirconocenes with O-Benzoylhydroxylamines: An Efficient Method for Synthesis of Enamines. Org. Lett. 2012, 14, 4750.

10. Yan, X.; Bouffard, J.; Guisado-Barrios, G.; Donnadieu, B.; Bertrand, G.* Anionic 1,2,3-Triazole-4,5-diylidene: A 1,2-Dihapto Ligand for the Construction of Bimetallic Complexes. Chem. -Eur. J. 2012, 18, 14627.

11. Yan, X.; Zhou, Y.; Xi, C.* Reactivity of alkynylzirconates towards allyl bromides: selective formation of b-allyl-zirconacyclopentadienes. Chem. Commun. 2010, 46, 7801.

12. Xi, C.*; Yan, X.; You, W.; Takahashi, T. Coupling Reactions of Zirconate Complexes Induced by Carbonyl Compounds. Angew. Chem. Int. Ed. 2009, 48, 8120.

13. Yan, X.; Lai, C.; Xi, C.* Zr-promoted linear coupling of alkynes to generate bis(allene)s. Chem. Commun. 2009, 6026.

14. Yan, X.; Yu, B.; Wang, L.; Tang, N.; Xi, C.* Reactivity of [(2-Phosphino)ethenyl]zirconocene Chloride toward CpM(CO)3Cl (M = Mo, W): Formation of [(3-Phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metal, {CpM(CO)2[(CO)CR=CRPPh2]} Organometallics 2009, 28, 6827.

15. Xi, C.;* Yan, X.; Lai, C; Kanno, K.; Takahashi, T. Regioselective Zirconophosphination of 1-Alkenes: A Versatile Route for the Synthesis of β-Functionalized Alkyldiphenylphosphine Oxides in the Presence of CuCl. Organometallics 2008, 27, 3834.

16. Yan, X.; Liu, Y.; Xi, C.* Palladaphosphacyclobutenes as catalysts in Heck and Suzuki reactions. Appl. Organomet. Chem. 2008, 22, 341.

17. Yan, X.; Xi, C.* Synthesis and Characterization of Novel Four-Membered Palladacycles. Organometallics 2008, 27, 152.

18. Xi, C.;* Yan, X.; Lai, C. Metallophosphination of Alkynes:  Efficient Synthesis of β-Functionalized Alkenylphosphines. Organometallics 2007, 26, 1084.

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